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Professur Anorganische Chemie
Mitarbeiter

Marcus Korb

Dr. Marcus Korb

Forschungsgebiet

Synthese planar-chiraler P,O-substituierter Ferrocene über eine anionische phospho-Fries Verschiebung

Veröffentlichungen

  1. Chlorido[1-diphenylphosphanyl-3-(phenylsulfanyl)propane-κ2P,S](η5-pentamethylcyclopentadienyl)iridium(III) chloride monohydrate.
    G. Ludwig, M. Korb, T. Rüffer, H. Lang, D. Steinborn, Acta Cryst. 2012, E68, m858.

  2. A Novel 1-Dimensional Coordination Polymer Bearing Tetrakis-Carboxylato Co(II)2 Units Interacting via P-Donors Based on 1-Carboxylic-1′-(Diphenylphosphino)Ferrocene.
    A. Aly, T. Rüffer, B. Bräuer, M. Korb, L. Sorace, H. Lang, Inorg. Chim. Acta 2012, 392, 404–409.

  3. Cationic arene ruthenium(II) complexes with chelating P-functionalized alkyl phenyl sulfide and sulfoxide ligands as potent anticancer agents.
    G. Ludwig, G.N. Kaluđerović, T. Rüffer, M. Bette, M. Korb, M. Block, R. Paschke, H. Lang, D. Steinborn, Dalton Trans. 2013, 42, 3771–3774.

  4. Synthesis and (Spectro)electrochemical Behavior of 2,5-Diferrocenyl-1-phenyl-1H-phosphole.
    D. Miesel, A. Hildebrandt, M. Korb, P.J. Low, H. Lang, Organometallics 2013, 32, 2993–3002.

  5. Tetrakis(ferrocenecarbonitrile) Copper(I) Complexes.
    F. Strehler, A. Hildebrandt, M. Korb, Heinrich Lang, Z. Anorg. Allg. Chem. 2013, 639, 1214–1219.

  6. A straightforward approach to oxide-free copper nanoparticles by thermal decomposition of a copper(I) precursor.
    D. Adner, M. Korb, S. Schulze, M. Hietschold, H. Lang, Chem. Commun. 2013, 49, 6855–6857.

  7. Biological activity of neutral and cationic iridium(III) complexes with κP and κPS coordinated Ph2PCH2S(O)xPh (x = 0–2) ligands.
    G. Ludwig, S. Mijatović, I. Ranđelović, M. Bulatović, D. Miljković, D. Maksimović-Ivanić, M. Korb, H. Lang, D. Steinborn, G.N. Kaluđerović, Eur. J. Med. Chem. 2013, 69, 216–222.

  8. Copper(II) and triphenylphosphine copper(I) ethylene glycol carboxylates: synthesis, characterisation and copper nanoparticle generation.
    D. Adner, S. Möckel, M. Korb, R. Buschbeck, T. Rüffer, S. Schulze, L. Mertens, M. Hietschold, M. Mehring, H. Lang, Dalton Trans. 2013, 42, 15599–15609.

  9. Metal–Metal Interaction in Fischer Carbene Complexes: A Study of Ferrocenyl and Biferrocenyl Tungsten Alkylidene Complexes.
    B. van der Westhuizen, J.M. Speck, M. Korb, J. Friedrich, D.I. Bezuidenhout, H. Lang, Inorg. Chem. 2013, 52, 14253–14263.

  10. Synthesis with Perfect Atom Economy: Generation of Furan Derivatives by 1,3-Dipolar Cycloaddition of Acetylenedicarboxylates at Cyclooctynes.
    K. Banert, S. Bochmann, A. Ihle, O. Plefka, F. Taubert, T. Walther, M. Korb, T. Rüffer, H. Lang, Molecules 2014, 9, 14022–14035.

  11. 3,4-Ferrocenyl-Functionalized Pyrroles: Synthesis, Structure, and (Spectro)Electrochemical Studies.
    M. Korb, U. Pfaff, A. Hildebrandt, T. Rüffer, H. Lang, Eur. J. Inorg. Chem. 2014, 1051–1061.

  12. Anticancer Potential of (Pentamethylcyclopentadienyl)chloridoiridium(III) Complexes Bearing κP and κPS-Coordinated Ph2PCH2CH2CH2S(O)xPh (x=0–2) Ligands.
    G. Ludwig, I. Ranđelović, D. Maksimović-Ivanić, S. Mijatović, M.Z. Bulatović, D. Miljković, M. Korb, H. Lang, D. Steinborn, G.N. Kaluđerović, ChemMedChem 2014, 9, 1051–1061.

  13. Di(biferrocenyl)ethyne and -butadiyne: Synthesis, properties and electron transfer studies.
    E.A. Poppitz, A. Hildebrandt, M. Korb, H. Lang, J. Organomet. Chem. 2014, 752, 133–140.

  14. Unusual Nitrile–Nitrile and Nitrile–Alkyne Coupling of Fc–C≡N and Fc–C≡C–C≡N.
    L. Becker, F. Strehler, M. Korb, P. Arndt, A. Spannenberg, W. Baumann, H. Lang, U. Rosenthal, Chem. Eur. J. 2014, 20, 3061–3068.

  15. Substituent Influence on Charge Transfer Interactions in α,α′-Diferrocenylthiophenes.
    J.M. Speck, M. Korb, T. Rüffer, A. Hildebrandt, H. Lang, Organometallics 2014, 33, 4813–4823.

  16. Synthesis of Unexpected Bifunctionalized Thiazoles by Nucleophilic Attack on Allenyl Isothiocyanate.
    B.J. Al-Hourani, F. Richter, K. Vrobel, K. Banert, M. Korb, T. Rüffer, B. Walfort, H. Lang, Eur. J. Org. Chem. 2014, 2899–2906.

  17. Anionic Phospho-Fries Rearrangement at Ferrocene: One-Pot Approach to P,O-Substituted Ferrocenes.
    M. Korb, D. Schaarschmidt, H. Lang, Organometallics 2014, 33, 2099–2108.

  18. Thio- and selenosulfonato complexes of iron bearing aromatic and heterocyclic groups.
    M. El-khateeb, K.J. Asali, M. Al-Noaimi, E. Al-Rabaee, F.F. Awwadi, D. Taher, M. Korb, H. Lang, Inorg. Chim. Acta 2014, 421, 553–558.

  19. Ferrocenyl-Based P,N Catalysts for the Mono-α-Arylation of Acetone.
    C. Gäbler, M. Korb, D. Schaarschmidt, A. Hildebrandt, H. Lang, Adv. Synth. Catal. 2014, 356, 2979–2983.

  20. Combining Cobalt-Assisted Alkyne Cyclotrimerization and Ring Formation through C–H Bond Activation: A “One-Pot” Approach to Complex Multimetallic Structures.
    G. Filipczyk, A. Hildebrandt, U. Pfaff, M. Korb, T. Rüffer, H. Lang, Eur. J. Inorg. Chem. 2014, 4258–4262.

  21. 1,3,5-Triferrocenyl-2,4,6-tris(ethynylferrocenyl)-benzene – a new member of the family of multiferrocenyl-functionalized cyclic systems.
    U. Pfaff, G. Filipczyk, A. Hildebrandt, M. Korb, H. Lang, Dalton Trans. 2014, 43, 16310–16321.

  22. Synthesis, Properties, and Electron Transfer Studies of Ferrocenyl Thiophenes.
    E.A Poppitz, A. Hildebrandt, M. Korb, D. Schaarschmidt, H. Lang, Z. Anorg. Allg. Chem. 2014, im Druck.

  23. Crystal structure of 3-(1′-(3,5-bis(trifluoromethyl)phenyl)-1,1′-ferrocenediyl)-4-bromothiophene.
    E.A. Poppitz, M. Korb, H. Lang, Acta Cryst. 2014, E70, 238–241.

  24. (Spectro)electrochemical investigations on (ferrocenyl)thiophenes modified by tungsten Fischer carbenes.
    B. van der Westhuizen, J.M. Speck, M. Korb, D.I. Bezuidenhout, H. Lang, J. Organomet. Chem. 2014, 772–773, 18–26.

  25. Planar Chirality from the Chiral Pool: Diastereoselective Anionic Phospho-Fries Rearrangements at Ferrocene.
    M. Korb, H. Lang, Organometallics 2014, 33, 6643–6659.

  26. Electronic Modification of Redox Active Ferrocenyl Termini and their Influence on the Electrontransfer Properties of 2,5-Diferrocenyl-N-Phenyl-1H-Pyrroles.
    S.W. Lehrich, A. Hildebrandt, M. Korb, H. Lang, J. Organomet. Chem. 2015, 792, 37–45.

  27. Unprecedented Synthesis of 2H,6H-1,5-Dithiocines Reinvestigated: A Structural Corrigendum Revealing Isothiazole-3(2H)-thiones.
    K. Banert, N. Singh, M. Korb, H. Lang, Synthesis 47 2015 533–537.

  28. Crystal structure of paddle-wheel sandwich-type [Cu2{(CH3)2CO}{μ-Fe(η5-C5H4C≡N)2}3](BF4)2·(CH3)2CO.
    F. Strehler, M. Korb, H. Lang, Acta Cryst. 2015, E71, 244–247.

  29. Crystal structure of ruthenocenecarbo­nitrile.
    F. Strehler, M. Korb, H. Lang, Acta Cryst. 2015, E71, 398–401.

  30. 1-Cyano-1′-ethynyl-ferrocene: Synthesis and reaction chemistry.
    F. Strehler, M. Korb, E.A. Poppitz, H. Lang, J. Organomet. Chem. 2015, 786, 1–9.

  31. Five-Membered Heterocycles as Linking Units in Strongly Coupled Homobimetallic Group 8 Metal Half-Sandwich Complexes.
    U. Pfaff, A. Hildebrandt, M. Korb, D. Schaarschmidt, M. Rosenkranz, A. Popov, H. Lang, Organometallics 2015, 34, 2826–2840

  32. Influence of P-Bonded Bulky Substituents on Electronic Interactions in Ferrocenyl-Substituted Phospholes.
    D. Miesel, A. Hildebrandt, M. Korb, D.A. Wild, P.J. Low, H. Lang, Chem. Eur. J. 2015, 21, 11545–11559.

  33. (Ferrocenylthienyl)phosphines for the Suzuki–Miyaura C,C coupling.
    C. Gäbler, M. Korb, D. Schaarschmidt, J.M. Speck, A. Hildebrandt, H. Lang, Inorg. Chem. Comm. 2015, 54, 96–99.

  34. Ferrocenes Bridged by Ethylenediamino Thiophene: Varying Charge Transfer Properties in a Series of 3,4-Di-N-substituted 2,5-Diferrocenyl Thiophenes.
    J. M. Speck, M. Korb, A. Schade, S. Spange, H. Lang, Organometallics 2015, 34, 3788–3798.

  35. Transition-Metal Carbonyl Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole.
    D. Miesel, A. Hildebrandt, M. Korb, D. Schaarschmidt, H. Lang, Organometallics 2015, 34, 4293–4304.

  36. Electronic Tuneable Dynamic and Electrochemical Behavior of N-(Diferrocenylmethylene)anilines
    S. Saloman, A. Hildebrandt, M. Korb, M. Schwind, H. Lang, ZAAC 2015, 641, 2282–2290.

  37. Intramolecular C–O Insertion of a Germanium(II) Salicyl Alcoholate: A Combined Experimental and Theoretical Study.
    P. Kitschke, T. Rüffer, M. Korb, H. Lang, W.B. Schneider, A.A. Auer, M. Mehring, Eur. J. Inorg. Chem. 2015, 5467–5479.

  38. Polyamide 6/silica hybrid materials by a coupled polymerization reaction.
    L. Kaßner, K. Nagel, R.E. Grützner, M. Korb, T. Rüffer, H. Lang, S. Spange, Polym. Chem. 2015, 6, 6297–6304.

  39. Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe([η]5-C5H4 cC4H3NPh)([η]5-C5H5)].
    U. Pfaff, M. Korb, H. Lang, Acta Cryst. 2016, E72, 92–95.

  40. Electronic interactions in gold(I) complexes of 2,5-diferrocenyl-1-phenyl-1H-phosphole.
    D. Miesel, A. Hildebrandt, M. Korb, H. Lang, J. Organomet. Chem. 2016, 803, 104–110.

  41. Crystal structure of (μ-1,4-dicarboxybutane-1,4-dicarboxylato)bis[bis(triphenylphosphane)silver(I)] dichloromethane trisolvate.
    P. Frenzel, M. Korb, H. Lang, Acta Cryst. 2016, E72, 215–219.

  42. Crystal structure of bis­[tetra­kis­(tri­phenyl­phosphane-κP)silver(I)] (nitrilo­tri­acetato-κ4N,O,O',O'') (tri­phenyl­phosphane-κP)argentate(I) with an unknown amount of methanol as solvate.
    J. Noll, M. Korb, H. Lang, Acta Cryst. 2016, E72, 318–321.

  43. Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers.
    M. Korb, P.J. Swarts, D. Miesel, A. Hildebrandt, J.C. Swarts, H. Lang, Organometallics 2016, 35, 1287–1300.

  44. A Reactivity Study of Phenyl and Ferrocenyl Phosphates Within the Anionic Phospho-Fries Rearangement.
    M. Korb, H. Lang, Inorg. Chem. Commun. 2016, 72, 30–32.

  45. Multi-Ferrocenyl Aryl Ethers - Applying the Nucleophilic Aromatic Substitution Reactions on Aryl fluorides.
    M. Korb, H. Lang, Eur. J. Inorg. Chem. 2017 276–287.

  46. Heterocyclic-based Ferrocenyl-Carboselenolates: Synthesis, Solid-State Structure and Electro-chemical Investigations
    D. Taher, F. F. Awwadi, J. M. Speck, M. Korb, D. Schaarschmidt, A. Habashneh, M. Al-Noaimi, M. El-khateeb, H. Lang, J. Organomet. Chem. 2016 eingereicht

  47. Bis(β-diketonato)- and allyl-(β-diketonato)-palladium(II) complexes: synthesis, characterization and MOCVD application.
    K. Assim, M. Melzer, M. Korb, T. Rüffer, A. Jakob, J. Noll, C. Georgi, S.E. Schulz, H. Lang,
    RSC Adv. 2016, 6, 102557–102569 .

  48. Multiferrocenyl Cobalt-Based Sandwich Compounds.
    G. Filipczyk, S. W. Lehrich, A. Hildebrandt, T. Rüffer, D. Schaarschmidt, M. Korb, H. Lang, Eur. J. Inorg. Chem. 2016 263–275 .

  49. Heterocyclic-based Ferrocenyl Carboselenolates: Synthesis, Solid-State Structure and Electrochemical Investigations.
    D. Taher, F. F. Awwadi, J. M. Speck, M. Korb, D. Schaarschmidt, S. Weheabby, A. Habashneh, M. Al-Noaimi, M. El-khateeb, S. T. Abu-Orabi, H. Lang, J. Organomet. Chem. 2017 im Druck (Sonderband G. van Koten)

  50. Bismuth(III) Anthranilates: Synthesis and Characterization of a Coordination Polymer and a Polynuclear Oxido Cluster.
    L. Wrobel, T. Rüffer, M. Korb, H. Lang und M. Mehring 2016 eingereicht

  51. Ferrocenyl Thiocarboxylates: Synthesis, Solid-state Structure and Electrochemical Investigations
    D. Taher, F. F. Awwadi, J. M. Speck, M. Korb, D. Schaarschmidt, C. Wagner, A. Habashneh, M. Al-Noaimi, M. El-kateeb, S. T. Abu-Orabi, K. Merzweiler, H. Lang, J. Organomet. Chem. 2017 (Sonderband 60iger Geburtstag J. Gladysz)

  52. Reactivity of Ferrocenyl Phosphates Bearing (Hetero-)Aromatics and [3]Ferrocenophanes toward Anionic Phospho-Fries Rearrangements.
    M. Korb, S. W. Lehrich, H. Lang, J. Org. Chem. 2017 .

  53. From Diferrocenyl-Cyclopropenone to Diferrocenyl-Cyclopropenylium Cations and Triferrocenyl-propenones: An Electrochemical Study
    S. W. Lehrich, A. Hildebrandt, M. Korb und H. Lang J. Organomet. Chem. 2017 im Druck (Sonderband 60. Geburtstag J. Gladysz)

  54. Ferrocenyl Silyl Ethers: Synthesis, Characterization and Electrochemical Investigation
    P. Frenzel, S. W. Lehrich, M. Korb, A. Hildebrandt und H. Lang J. Organomet. Chem. 2017 im Druck (Sonderband 75. Geburtstag G. van Koten)

  55. Synthesis, Electrochemistry, and Optical Properties of Half-Sandwich Ruthenium Complexes Bearing Triarylamine-Anthracenes.
    E. Kovalski, M. Korb und A. Hildebrandt Eur. J. Inorg. Chem. 2018, 671–675.

  56. β-Ketoiminato-based Copper(II) Complexes as CVD Precursors for Copper and Copper Oxide Layer Formation.
    E. Pousaneh, M. Korb, V. Dzhagan, M. Weber, J. Noll, M. Mehring, D. R. T. Zahn, S. E. Schulz, H. Lang, Dalton Trans. 2018, 47, 10002–10016

  57. (Planar-Chiral) Ferrocenylmethanols: From Anionic Homo Phospho-Fries Rearrangements to α-Ferrocenyl Carbenium Ions.
    M. Korb, J. Mahrholdt, H. Lang, Eur. J. Inorg. Chem. 2017, 4028–4048

  58. Reactivity of Planar-Chiral α-Ferrocenyl Carbocations towards Electron-Rich Aromatics.
    M. Korb, J. Mahrholdt, X. Liu, H. Lang, Eur. J. Inorg. Chem. 2018, 973–987

Vorträge

  1. Ein neuer Zugang zu 1,2-P,O Ferrocenen — die anionische phospho-Fries Verschiebung.
    M. Korb, H. Lang, FCI Stipendiatentreffen, 17.12.2013, FSU Jena.

  2. The Anionic Phospho-Fries Rearrangement: A Brilliant approach to 1,2-P,O-substituted Ferrocenes.
    M. Korb, H. Lang, 12th Ferrocene Colloquium, 17.–19.02.2014, Innsbruck.

  3. The Anionic Phospho-Fries Rearrangement: A new approach to 1,2-P,O-substituted Ferrocenes.
    M. Korb, H. Lang, 12. Mitteldeutsches Anorganiker-Nachwuchssymposium, 11.09.2014, Freiberg.

  4. The Anionic Phospho-Fries Rearrangement: A new approach to 1,2-P,O-substituted Ferrocenes.
    M. Korb, H. Lang, 6. JCF/GDCh/NES/CAS-Studienreise, 250th ACS National Meeting & Exposition, 16.08.2015, Bosten.

Poster

  1. Chiral Alkenylferrocenes in Suzuki-Miyaura C,C-Couplings.
    D. Schaarschmidt, M. Korb, H. Lang, 7th Heidelberg Forum of Molecular Catalysis, 28.06.2013, Heidelberg.

  2. Ein neuer Zugang zu 1,2-P,O Ferrocenen — die anionische phospho-Fries Verschiebung.
    M. Korb, H. Lang, FCI Stipendiatentreffen, 17.12.2013, FSU Jena.

  3. 1,2-P,O-Ferrocenes in Suzuki-Miyaura C,C-couplings.
    M. Korb, H. Lang, 47. Jahrestreffen deutscher Katalytiker, 12.–14.03.2014, Weimar.

  4. Synthesis of a Porphyrin based on 3,4-Diferrocenyl-Pyrrole.
    M. Korb, H. Lang, 11th Ferrocene Colloquium, 06.–08.02.2013, Hannover.

  5. 1,2-P,O-ferrocenes in Suzuki-Miyaura C,C-coupling.
    M. Korb, H. Lang, 5th EuCheMS, 31.08.–04.09.2014, Istanbul.

  6. The electronic properties of ferrocenyl aryl ethers – adjusted with anionic Fries rearrangements.
    M. Korb, D. Miesel, P. Swarts, H. Lang, 13th Ferrocene Colloquium, 22.–24.02.2015, Leipzig.